Anomalous diffusion governed by a fractional diffusion equation and the electrical response of an electrolytic cell.

نویسندگان

  • P A Santoro
  • J L de Paula
  • E K Lenzi
  • L R Evangelista
چکیده

The electrical response of an electrolytic cell in which the diffusion of mobile ions in the bulk is governed by a fractional diffusion equation of distributed order is analyzed. The boundary conditions at the electrodes limiting the sample are described by an integro-differential equation governing the kinetic at the interface. The analysis is carried out by supposing that the positive and negative ions have the same mobility and that the electric potential profile across the sample satisfies the Poisson's equation. The results cover a rich variety of scenarios, including the ones connected to anomalous diffusion.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Anomalous diffusion and memory effects on the impedance spectroscopy for finite-length situations.

The contribution of ions to the electrical impedance of an electrolytic cell limited by perfect blocking electrodes is determined by considering the role of the anomalous diffusion process and memory effects. Analytical solutions for fractional diffusion equations together with Poisson's equation relating the effective electric field to the net charge density are found. This procedure allows th...

متن کامل

New Insights into the Fractional Order Diffusion Equation Using Entropy and Kurtosis

Fractional order derivative operators offer a concise description to model multi-scale, heterogeneous and non-local systems. Specifically, in magnetic resonance imaging, there has been recent work to apply fractional order derivatives to model the non-Gaussian diffusion signal, which is ubiquitous in the movement of water protons within biological tissue. To provide a new perspective for establ...

متن کامل

An Implicit Difference-ADI Method for the Two-dimensional Space-time Fractional Diffusion Equation

Fractional order diffusion equations are generalizations of classical diffusion equations which are used to model in physics, finance, engineering, etc. In this paper we present an implicit difference approximation by using the alternating directions implicit (ADI) approach to solve the two-dimensional space-time fractional diffusion equation (2DSTFDE) on a finite domain. Consistency, unconditi...

متن کامل

A New Implicit Finite Difference Method for Solving Time Fractional Diffusion Equation

In this paper, a time fractional diffusion equation on a finite domain is con- sidered. The time fractional diffusion equation is obtained from the standard diffusion equation by replacing the first order time derivative by a fractional derivative of order 0 < a< 1 (in the Riemann-Liovill or Caputo sence). In equation that we consider the time fractional derivative is in...

متن کامل

Finite integration method with RBFs for solving time-fractional convection-diffusion equation with variable coefficients

In this paper, a modification of finite integration method (FIM) is combined with the radial basis function (RBF) method to solve a time-fractional convection-diffusion equation with variable coefficients. The FIM transforms partial differential equations into integral equations and this creates some constants of integration. Unlike the usual FIM, the proposed method computes constants of integ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • The Journal of chemical physics

دوره 135 11  شماره 

صفحات  -

تاریخ انتشار 2011